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磁性材料等能源、工程材料的中子散射研究

发布日期：2021-09-08　　 　　点击量：

（一）北京大学高强度粉末中子衍射仪（PKU-HIPD）建设

基于中子不带电、能量低、有磁矩、穿透性强等特点，中子衍射仪具有常规探测技术（XRD、电子衍射等）不具备的优势，是凝聚态物理、材料科学等研究领域的尖端探测设备。我课题组依托中国原子能科学研究院国家大科学装置中国先进研究堆（CARR）与美国密苏里大学和中国原子能科学研究院共同建设了北京大学高强度粉末中子衍射仪（PKU-HIPD）。

PKU-HIPD最佳分辨率为千分之二。双聚焦中子单色器和位置灵敏探测器的使用大大提高了中子利用率。相比于常规的中子衍射仪，北京大学高强度中子衍射仪具有在满足较高分辨水平的条件下将探测效率数倍提高的优势，填补了我国高强度谱仪的空白。这个项目将大大推动我国相关基础科学研究和工业技术应用的发展，同时开创了我国高等院校和科研机构共同建设国家大科学工程平台的先例，为充分利用国家大科学装置开展科学研究提供了良好的基础。

中国先进研究堆（CARR）由中国原子能科学研究院自主研发、设计和建造，是一座高性能、多用途、安全可靠的核反应堆装置，并配套相关实验终端，可开展核物理与核化学等基础科学和相关应用研究。反应堆功率为60MW，重水反射层最高未扰热中子注量率达8×1014n/cm2•s，在同类中子束流研究堆中其主要技术指标位居于亚洲第一，世界前列。

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（二）磁结构与相变研究

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（三）Li/Na离子电池材料研究

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发表文章列表

2020年

  1. Lin, Z., Zha, L., Wang, F., Liu, Z., Wu, R., Yang, J., Xue, M., Yang, W., Tian, G., Ma, X., Qiao, L., Franz, A., An, Q., Liu, W., Wang, C., Yang, J. Effect of Ce substitution on the structural and magnetic properties of Nd2Fe14B (2020) Acta Materialia, 200, pp. 502-509. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85091057995&doi=10.1016%2fj.actamat.2020.08.084&partnerID=40&md5=c2edd643cfc9c68944a143189aba7e3b [IF=7.656]

  2. Kong, W., Yang, W., Ning, D., Li, Q., Zheng, L., Yang, J., Sun, K., Chen, D., Liu, X. Tuning anionic/cationic redox chemistry in a P2-type Na0.67Mn0.5Fe0.5O2 cathode material via a synergic strategy [通过一种协同策略调节P2型Na0.67Mn0.5Fe0.5O2正极材料的阴/阳离子氧化还原反应] (2020) Science China Materials, 63 (9), pp. 1703-1718. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85085219720&doi=10.1007%2fs40843-020-1318-4&partnerID=40&md5=dddc0cf0bf91ada3dd9af8d2275310e1 [IF=6.098]

  3. Peng, Y., Cheng, X., Gu, P., Wang, F., Yang, J., Xue, M., Yang, W., Wang, C., Liu, S., Watanabe, K., Taniguchi, T., Ye, Y., Yang, J. A Quaternary van der Waals Ferromagnetic Semiconductor AgVP2Se6 (2020) Advanced Functional Materials, 30 (34), 论文编号 1910036, . https://www.scopus.com/inward/record.uri?eid=2-s2.0-85087307938&doi=10.1002%2fadfm.201910036&partnerID=40&md5=0491fa443d42d205c0ccc99aa82fba84 [IF=16.836]

  4. Xiang, X., Liu, Y., Chen, F., Yang, W., Yang, J., Ma, X., Chen, D., Su, K., Shen, Q., Zhang, L. Crystal structure and lithium ionic transport behavior of Li site doped Li7La3Zr2O12 (2020) Journal of the European Ceramic Society, 40 (8), pp. 3065-3071. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081273758&doi=10.1016%2fj.jeurceramsoc.2020.02.054&partnerID=40&md5=a5ac9e7e4b20a1d0b61fac974b007fef [IF= 4.495]

  5. Peng, Y., Ding, S., Cheng, M., Hu, Q., Yang, J., Wang, F., Xue, M., Liu, Z., Lin, Z., Avdeev, M., Hou, Y., Yang, W., Zheng, Y., Yang, J. Magnetic Structure and Metamagnetic Transitions in the van der Waals Antiferromagnet CrPS4 (2020) Advanced Materials, 32 (28), 论文编号 2001200 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85085943152&doi=10.1002%2fadma.202001200&partnerID=40&md5=5b1fb94c4b4d528e570e1cd8aad760fd [IF=27.398]

  6. Wang, Z., Yang, W., Yang, J., Zheng, L., Sun, K., Chen, D., Sun, L., Liu, X. Tuning the crystal and electronic structure of Li4Ti5O12 via Mg/La Co-doping for fast and stable lithium storage (2020) Ceramics International, 46 (9), pp. 12965-12974. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85079426416&doi=10.1016%2fj.ceramint.2020.02.066&partnerID=40&md5=c6c78476433ee333b4bb36375361c083 [IF= 3.83]

  7. Xu, J., Zheng, X., Yang, S., Yang, S., Xi, L., Wang, S., Zhang, L., Yang, W., Yang, J., Ma, X., Chen, D., He, L., He, L., He, L., He, L., Deng, S., Zhang, J., Wu, Y., Shen, B., Shen, B., Shen, B. Large Linear Negative Thermal Expansion in NiAs-type Magnetic Intermetallic Cr-Te-Se Compounds. (2020) Inorganic Chemistry, 59 (12), pp. 8603-8608. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85085681956&doi=10.1021%2facs.inorgchem.0c01048&partnerID=40&md5=4d055bae7d5779410f8839e996ab2ed4 [IF= 4.825]

  8. Xiang, X., Chen, F., Yang, W., Yang, J., Ma, X., Chen, D., Su, K., Shen, Q., Zhang, L. Dual regulation of Li+ migration of Li6.4La3Zr1.4M0.6O12 (M = Sb, Ta, Nb) by bottleneck size and bond length of M−O (2020) Journal of the American Ceramic Society, 103 (4), pp. 2483-2490. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85076155645&doi=10.1111%2fjace.16920&partnerID=40&md5=e0789e4f639d64a662fcc5f30ee8aea7 [IF= 3.502]

  9. Zhai, Y., Yang, W., Ning, D., Yang, J., Sun, L., Schuck, G., Schumacher, G., Liu, X. Improving the cycling and air-storage stability of LiNi0.8Co0.1Mn0.1O2 through integrated surface/interface/doping engineering (2020) Journal of Materials Chemistry A, 8 (10), pp. 5234-5245. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081623429&doi=10.1039%2fc9ta13014d&partnerID=40&md5=b5fb45f3f8d7ab67d6dd828fa2d3fef8 [IF= 11.301]

  10. Qiu, Y., Gao, R., Yang, W., Huang, L., Mao, Q., Yang, J., Sun, L., Hu, Z., Liu, X. Understanding the Enhancement Mechanism of A-Site-Deficient LaxNiO3 as an Oxygen Redox Catalyst (2020) Chemistry of Materials, 32 (5), pp. 1864-1875. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081893845&doi=10.1021%2facs.chemmater.9b04287&partnerID=40&md5=8660f89272a9bcd258c9462d181bc214 [IF= 9.567]

  11. Yang, W.-Y., Liang, D., Kong, X.-D., Yang, J.-B. Neutron diffraction studies of permanent magnetic materials (2020) Rare Metals, 39 (1), pp. 13-21. https://www.scopus.com/inward/record.uri?eid=2-s2.0-85070797199&doi=10.1007%2fs12598-019-01300-8&partnerID=40&md5=c6ccc790676979d4d66d62caa73139bc [IF=1.785]

2019年

  1. Rui Wang, Guoyu Qian, Tongchao Liu, Maofan Li, Jiajie Liu, Bingkai Zhang, Weiming Zhu, Shuankui Li, Wenguang Zhao, Wenyun Yang, Xiaobai Ma, Zhendong Fu, Yuntao Liu, Jinbo Yang, Lei Jin, Yinguo Xiao, Feng Pan. Tuning Li-Enrichment in High-Ni Layered Oxide Cathodes to Optimize Electrochemical Performance for Li-Ion Battery. Nano Energy 62 (2019) 709-717. (Impact Factor: 15.548)

  2. Weijin Kong, Rui Gao, Qingyuan Li, Wenyun Yang, Jinbo Yang, Limei Sun, Xiangfeng Liu. Simultaneously tuning cationic and anionic redox in P2-Na0.67Mn0.75Ni0.25O2cathode material through a synergic Cu/Mg co-doping. JOURNAL OF MATERIALS CHEMISTRY A 7 (2019) 9099-9109. (Impact Factor: 10.733)

  3. Qianjiang Mao,Cheng Zhang,Wenyun Yang, Jinbo Yang, Limei Sun, Yongmei Hao, Xiangfeng Liu. Mitigating the voltage fading and lattice cell variations of O3-NaNi0.2Fe0.35Mn0.45O2for high performance Na-ion battery cathode by Zn doping. Journal of Alloys and Compounds 794 (2019) 509-517. (Impact Factor: 4.175)

  4. Limei Sun,Zhongxiao Liu, Zhenya Wang, Wenyun Yang, Jinbo Yang, Kai Sun, Dongfeng Chen , Yuntao Liu, Xiangfeng Liu.The synergic effects of Ca and Sm co-doping on the crystal structure and electrochemical performances of Li4-xCaxTi5-xSmxO12anode material. Solid State Sciences 87 (2019) 110-117. (Impact Factor: 2.155)

  5. Zhenya Wang, Limei Sun, Wenyun Yang, Jinbo Yang, Kai Sun, Dongfeng Chen, Xiangfeng Liu, Unveiling the Synergic Roles of Mg/Zr Co-Doping on Rate Capability and Cycling Stability of Li4Ti5O12. Journal of the Electrochemical Society 166 (2019) A658-A666. (Impact Factor: 3.12)

2018年

  1. Zhengyao Li, Huibo Wang, Wenyun Yang, Jinbo Yang, Lirong Zheng, Dongfeng Chen, Kai Sun, Songbai Han, Xiangfeng Liu, Modulating the Electrochemical Performances of Layered Cathode Materials for Sodium-Ion Batteries through Tuning Coulombic Repulsion between Negatively Charged TMO2Slabs. ACS Applied Materials & Interfaces 10(2018) 1707−1718. (Impact Factor: 8.456)

  2. Zhengyao Li, Huibo Wang, Dongfeng Chen, Kai Sun, Wenyun Yang, Jinbo Yang, Xiangfeng Liu, and Songbai Han, Improving the Performance of Layered Oxide Cathode Materials with Football-Like Hierarchical Structure for Na-Ion Batteries by Incorporating Mg2+into Vacancies in Na-ion Layers. ChemSusChem 11 (2018) 1223–1231. (Impact Factor: 7.804)

  3. Huibo Wang, Zhengyao Li, Wenyun Yang, Jinbo Yang, Dongfeng Chen, Chunjian Su, Xiangfeng Liu, Structure modulation and performance optimization of P2-Na0.7Mn0.75Fe0.25-x-yNixCoyO2through a synergistic substitution of Ni and Co for Fe. Electrochimica Acta 277 (2018) 88-99. (Impact Factor: 5.383)

  4. Wenyun Yang, Hui Zhao, Youfang Lai, Guanyi Qiao, Yuanhua Xia, Honglin Du, Jingzhi Han, Changsheng Wang, Shunquan Liu, Yingchang Yang, Yanglong Hou, Jinbo Yang, Study on the Performance of the Neutron Diffractometer (HIPD at CARR) by Monte Carlo Simulation and Convolution Methods, IEEE Transactions on Nuclear Science 65 (2018) 1324-1330. (Impact Factor: 1.428)

2017年

  1. Hui Zhao, Wenyun Yang, Zhuyin Shao, Guang Tian, Dong Zhou, Honglin Du, Shunquan Liu, Jingzhi Han, ChangshengWang, Jing Xu, Dunbo Yu, Yingchang Yang, Jinbo Yang, Structural evolution, site ordering and magnetic properties of tetragonal Mn6-yGa2+y(0 ≤ y ≤ 1.64). Scripta Materialia 129 (2017) 6-10. (Impact Factor: 4.539)

2016年

  1. Xinzhi Liu, LijieHao, YuntaoLiu, XiaobaiMa, SiqinMeng, YuqingLi, JianboGao, Hao Guo, WenzeHan, KaiSun, MeimeiWu, XipingChen, LeiXie, FrankKlose, Dongfeng Chen, Neutron powder diffraction investigation of magnetic structure and spin reorientation transition of HoFe1-xCrxO3solid solutions. Journal of Magnetism and Magnetic Materials 417 (2016) 382–388. (Impact Factor: 2.683)

  2. Hui Zhao, Wenyun Yang, Zhuyin Shao, Guang Tian, Dong Zhou, Xiping Chen, Yuanhua Xia, Lei Xie, Shunquan Liu, Honglin Du, Jingzhi Han, Changsheng Wang, Yingchang Yang, Jinbo Yang, Structural evolution and magnetic properties of L10-type Mn54.5Al45.5-xGax(x = 0.0, 15.0, 25.0, 35.0, 45.5) phase. Journal of Alloys and Compounds 680 (2016) 14-19. (Impact Factor: 4.175)

  3. Wenze Han, Hao Guo, Kai Sun, Demin Chen, Shi Liu, Erdong Wu, Yuntao Liu, Dongfeng Chen, Structure of LaNi3.8AlMn0.2Compounds Studied by Neutron Powder Diffraction. Materials Science Forum 847 (2016) 26-28. (Impact Factor: 0)

  4. Hao Guo, Wenze Han, Kai Sun, Demin Chen, Shi Liu,Erdong Wu, Yuntao Liu and Dongfeng Chen, Structure of LaNi3.8AlMn0.2D3.2Compound Studied by Neutron Powder Diffraction. Materials Science Forum 847 (2016) 22-25. (Impact Factor: 0)

2015年

  1. Zhongxiao Liu, Limei Sun, Wenyun Yang, Jinbo Yang,Songbai Han, Dongfeng Chen, Yuntao Liu, Xiangfeng Liu, The synergic effects of Na and K co-doping on the crystal structure and electrochemical properties of Li4Ti5O12as anode material for lithium ion battery. Solid State Sciences 44 (2015) 39-44. (Impact Factor: 2.155)

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